benzene on the basis of the three-electron bond 30, graphite
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benzene on the basis of the three-electron bond, graphite.
From these equations we find:
c\u2013c benzene multiplicity (L = 1.397 A) = 1.658
c\u2013c graphite multiplicity (L = 1.42 A) = 1.538 \u2248 1.54
Ec\u2013c benzene (L = 1.397 A) = 534.0723 kj/mole
Ec\u2013c graphite (L = 1.42 A) = 503.3161 kj/mole.
The fact of the distance between the graphite layers being 3.35 A (the \u0421-\u0421 bond
length inside the layer making 1.42 A) may serve as an indirect confirmation of the
possibility of interaction of the electrons through the cycle in benzene. This causes a weak bond between the layers and, as a result, the ability of the layers to shift relative to each other. Since the distance between the central electrons in benzene is less and makes 2.420 A (in case of an interaction through the cycle), we should expect a stronger interaction.
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