Benzene with three-electron bond. W. O. Kermak and R. Robinson, J. J. Thomson.
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Benzene with three-electron bond. W.O. Kermak and R. Robinson, J. J. Thomson.I note that the three-electron bond to describe the benzene molecule used even
W.O. Kermak, R. Robinson and J. J. Thomson at the beginning of the 20th century.
Here are links to their works:
1. Thomson, J. J. Philosophical Magazine, 1921, 41, 510-538.
2. W.O. Kermak and R. Robinson, J. Chem. Soc. 427 (1922).
But since it is not taken into account the spin of electrons, we have already started
cyclooctatetraene problems and therefore the description of the benzene molecule
by a three-electron proved unsuccessful.
Using the three-electron bond with multiplicity of 1.5 and take account of the spin
of each electron leads to very good results in the description of the benzene
molecule and explain the aromaticity in general. With the help of three-electron
bond with multiplicity of 1.5 can be represented by a real formula of many organic
and inorganic molecules without the aid of virtual structures.
The present work shows the inapplicability of the Pauli principle to chemical bond, and a new theoretical model of the chemical bond is proposed based on the Heisenberg uncertainty principle. See pp. 88 - 104 Review (135 pages, full version). Benzene on the Basis of the Three-Electron Bond. (The Pauli exclusion principle, Heisenberg's uncertainty principle and chemical bond). http://vixra.org/pdf/1710.0326v3.pdf
Benzene on the basis of the three-electron bond:
Review (135 pages, full version). Benzene on the Basis of the Three-Electron Bond. (The Pauli exclusion principle, Heisenberg's uncertainty principle and chemical bond). http://vixra.org/pdf/1710.0326v3.pdf
1. Structure of the benzene molecule on the basis of the three-electron bond.
http://vixra.org/pdf/1606.0152v1.pdf
2. Experimental confirmation of the existence of the three-electron bond and theoretical basis ot its existence.
http://vixra.org/pdf/1606.0151v2.pdf
3. A short analysis of chemical bonds.
http://vixra.org/pdf/1606.0149v2.pdf
4. Supplement to the theoretical justification of existence of the three-electron bond.
http://vixra.org/pdf/1606.0150v2.pdf
5. Theory of three-electrone bond in the four works with brief comments.
http://vixra.org/pdf/1607.0022v2.pdf
6. REVIEW. Benzene on the basis of the three-electron bond. http://vixra.org/pdf/1612.0018v5.pdf
7. Quantum-mechanical aspects of the L. Pauling's resonance theory.
http://vixra.org/pdf/1702.0333v2.pdf
8. Quantum-mechanical analysis of the MO method and VB method from the position of PQS.
http://vixra.org/pdf/1704.0068v1.pdf
9. Review (135 pages, full version). Benzene on the Basis of the Three-Electron Bond. (The Pauli exclusion principle, Heisenberg's uncertainty principle and chemical bond). http://vixra.org/pdf/1710.0326v3.pdf
Bezverkhniy Volodymyr (viXra): http://vixra.org/author/bezverkhniy_volodymyr_dmytrovych
Bezverkhniy Volodymyr (Scribd):
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